I just use TeX, never LaTeX. With TeX, the documentation is shorter and, IMHO, better written. That is, get to concentrate on just Knuth's The TeXBook -- nicely done technical writing.
With LaTeX, I suspect that really should also know the underlying TeX, but with some understanding of TeX can do just fine without LaTeX and all its extra considerations.
With LaTeX, I suspect that really should also know the underlying TeX, but with some understanding of TeX can do just fine without LaTeX and all its extra considerations.