Shipping Win64 builds by default to a wider group of users is a high priority in 2017 (stability being a big driver of it), but there's still some bugs blocking it. The work is being tracked at https://bugzilla.mozilla.org/show_bug.cgi?id=558448 and various dependencies.
FYI, this default has been flipped on Nightly, and that change should make it in to the version 53 release in April (barring any huge problems found in the 64-bit build).
For Linux and MacOS it's been available for a long time.
I've also used the 64-bit Firefox on my Windows for some time now, but it's not the default download that they offer. See it here: https://www.mozilla.org/en-US/firefox/all/
In fact, 64-bit Mac will be the only version supported as of Firefox 53. This will halve the Mac installer size. 32-bit and Universal Mac builds were dropped in Firefox bug 1295375: https://bugzil.la/1295375
The installer from https://www.mozilla.org/en-US/firefox/ defaults to 32-bit, what would you expect?