My dad takes clients out to lunch a few times a week. He always tips the server with $2 bills. Every server on his side of town remembers him, and his favorite drinks, meals, etc. (and really impresses the clients!)
When I used to work as a valet it was a big deal every time we got a $2 bill in tip. When we were splitting the tip we would always ask if any of the new guys had never gotten one before and make sure they got one.
There was a factory in a town somewhere that paid all its workers' bonuses in $2 bills so that the town could see the effect that the factory had on the local economy.
My son is in kindergarten and one of his Vietnamese classmates gave everyone a red envelope with a $2 in it for Lunar New Year. I have also received a similar gift from a Chinese co-worker, so maybe that's where some are going?
My recollection of the story is that he would laminate them into "tablets" with rubber cement and then tear off the top sheet(s) to make a payment. I think I have that story bookmarked somewhere.
EDIT: I'm not sure where the "printing" part of this story comes into play but it looks like his tablets do indeed have multiple bills per sheet in addition to being laminated at the top. (https://hackaday.com/2012/08/03/woz-prints-and-spend-his-own...)