Where is this "maximize"? Is it an add-on? A button I'm not seeing?
edit: why the downvotes? I'm at work on my rickety WinXP corporate box, and FF4 definitely does not behave as described above. (Do really think I didn't try that?!)
Press the little button in the titlebar that makes any window fill the screen.
Note that tabs will appear in the titlebar when maximized on Windows only, for Firefox 4, and only if you have the menu bar hidden. (It's hidden by default in Windows Vista and 7.) Tabs in the titlebar are planned for Mac and Linux too, but weren't ready for this release.