I think the most important part would be to give someone time to vet that it's legitimate. Stack Exchange has on the order of 100 developers, it wouldn't be hard to CC account creation or password reset notices to the manager of a new hire, and in that case, 10 minutes would often be enough to say "Uh, I haven't hired anyone named Curious Llama, who are they and why are they requesting developer access to an obsolete resource?" and put the brakes on.