SICP is mainly a book about how to structure systems. It also tells you how languages work, but in far less detail.
PLAI (this book) teaches you how languages work. It also tells you a bit about how to structure systems, but that is not its goal. In part that is not a goal because of the existence of books like SICP and, increasingly, DCIC [https://dcic-world.org/].
You are right. I have now binged 2/3 of PLAI. It is really nice in how it draws the landscape of programming languges and how they work. It of course also has an advantage being a newer book, programming languages and their theory have progressed quite a lot since writing of SICP.
Also it is some how pedagogically really nice, very approachable and readable.