Better-read with good probability, better-educated with good probability. But no specific reason for them to be more intelligent, because there is no process to make that especially likely.
It is a job one gets by deciding to do it, sticking to it, paying one's dues over a long period, cultivating connections, building a personal brand. Like so many other jobs...
Professors should be respected in direct proportion to their actually demonstrated knowledge, and only in the fields where that knowledge has been demonstrated... other than this we should not respect them more than teachers of high school or elementary school, who usually have greater expertise and dedication in teaching.