TBH at this point the failure modes in which 1.1.1.1 would go down and 1.0.0.1 would not are not that many. At CloudFlare’s scale, it’s hardly believable a single of these DNS servers would go down, and it’s rather a large-scale system failure.
But I understand why Cloudflare can’t just say “use 8.8.8.8 as your backup”.
It would depend on how Cloudflare set up their systems. From this and other outages, I think it's pretty clear that they've set up their systems as a single failure domain. But it would be possible for them to have setup for 1.1.1.1 and 1.0.0.1 to have separate failure domains --- separate infrastructure, at least some sites running one but not the other.