A really handy one a colleague showed me yesterday was the /dev/fd/0|1|2 files, which are stdin/out/err respectively.
Means you can use that file for utils that expect a file only.
E.g echo "This would be contents of file" | someCommand /dev/fd/0
You can even access the file descriptors of other processes with /proc/${pid}/fd/; which is handy for (say) un-deleting a file that a process still has open.
Another handy one is "process substitution" which lets you do the same thing with multiple streams by creating new file descriptors, and automatically turning them into /dev/fd/* paths:
someCommand <(echo "contents of file 1") <(echo "contents of file 2")
which is somewhat explained by:
$ echo someCommand <(echo "contents of file 1") <(echo "contents of file 2")
someCommand /dev/fd/63 /dev/fd/62
"process substitution" is one of the new useful things I learned this year (switched to bash from csh over 20 years ago).
/proc/${pid}/fd/ is very useful for forensic purposes when you find some malware running that deleted itself and/or config files but still has a handle open to them.
E.g echo "This would be contents of file" | someCommand /dev/fd/0